A Starter Pokemon.
Blaziken was first seen in Pop Goes The Sneasel. Harrison used it to defeat the Sneasel that was blocking access to the flame of Ho-Oh. Harrison later used Blaziken in a climactic battle with Ash's Charizard.
In Once More with Reeling, May's Combusken evolved into a Blaziken. She brought it with her to Johto, and it was one of the Pokémon she used when she returned in A Full Course Tag Battle!.
A Blaziken was also seen in Destiny Deoxys under the ownership of Rafe.
Its Mega Evolution debuted in Kalos, Where Dreams and Adventures Begin!. It has continued to appear throughout the series, mostly within Lumiose City, but also in Mega-Mega Meowth Madness! where its trainer, Blaziken Mask, is revealed to be Meyer in disguise.
Another Blaziken that can Mega Evolve into Mega Blaziken is set to appear in Mega Evolution Special II.
Another Blaziken appeared in Last Call — First Round!. It was used with a Sceptile in a coordinator's appeal.
A Blaziken appeared in Alexa's magazine in The Journalist from Another Region!.
A Blaziken that can Mega Evolve into Mega Blaziken appeared in Mega Evolution Special I.
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